Manganese could make luminescent materials and the conversion of sunlight more sustainable

Smartphone screens and catalysts for artificial photosynthesis – to produce fuels from sunlight, for example – often contain very rare metals. Iridium, for instance, which is used in organic light-emitting diodes (OLEDs), is rarer than gold or platinum. Ruthenium, used in solar cells, is also one of the rarest stable elements. These metals are not only very expensive, by virtue of their scarcity, but also toxic in many compounds.

Now, a team led by Professor Oliver Wenger and his doctoral student Patrick Herr from the University of Basel have for the first time succeeded in producing luminescent manganese complexes in which exposure to light causes the same reactions to take place as in ruthenium or iridium compounds. The findings have been published in the journal Nature Chemistry. The advantage of using manganese is that the element is 900,000 times more abundant in the Earth’s crust than iridium, as well as being significantly less toxic and many times cheaper.

Rapid photochemistry

At present, the new manganese complexes perform worse than iridium compounds in terms of their luminous efficiency. However, the light-driven reactions that are needed for artificial photosynthesis such as energy- and electron-transfer reactions take place at high speed. This is due to the special structure of the new complexes, which leads to an immediate charge transfer from the manganese toward its direct bonding partners on excitation with light. This design principle for complexes is already used in certain types of solar cells, although until now it has mostly featured noble metal compounds, and sometimes complexes based on the less noble metal copper.

Preventing unwanted vibrations

The absorption of light energy normally causes greater distortion in complexes made of cheap metals than it does in noble metal compounds. As a result, the complexes begin to vibrate and a large part of the absorbed light energy is lost. The researchers were able to suppress these distortions and vibrations by incorporating tailor-made molecular components into the complexes in order to force the manganese into a rigid environment. This design principle also increases the stability of the resulting compounds and their resistance to decomposition processes.